Hydrogenation of polyaromatic compounds over NiCo/chrysotile catalyst

نویسندگان

چکیده

The activity and selectivity of the bimetallic NiCo/chrysotile catalyst during hydrogenation model objects (anthracene phenanthrene) for 1 hour at an initial hydrogen pressure 3 MPa a temperature 400 °C were studied. chrysotile mineral used as substrate active centers nickel cobalt is waste product asbestos production Kostanay Minerals JSC (the Republic Kazakhstan). was characterized by complex methods physical chemical analysis. consists nanotubes with inner diameter about 10 nm outer 60 nm. amount products 61.91 %, destruction — 15.08 % isomerization 8.37 anthracene. 26.09 that 2.51 phenanthrene. It found selectively accelerates reaction allows increasing yields products. schemes drawn up according to results gas chromatography-mass spectrometric analysis hydrogenates.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Simultaneous Hydrogenation of Multiring Aromatic Compounds over NiMo Catalyst

Hydrogenation of six model feeds containing three-, two-, and one-ring aromatic compounds was investigated to gain insights into the aromatic hydrogenation reaction chemistry over a commercial NiMo catalyst under practical reaction conditions. The hydrogenation reactivity of the aromatic compounds followed the following order: phenanthrene ∼ two-ring aromatics . one-ring aromatic. Comparison wi...

متن کامل

Liquid Phase Hydrogenation of Aromatic Compounds on Nickel Catalyst

...........................................................................................................1 Preface.............................................................................................................3 List of Publications ...........................................................................................4

متن کامل

Partial acetylene hydrogenation over commercial Pd-Ag/α-Al2O3 catalyst promoted by ionic liquid

1-butyl-3-methyl imidazolinium hydroxide ionic liquid (BMIm[OH]) is loaded on commercial low surface area Pd-Ag/α-Al2O3 solid ‎catalyst to enhance higher selectivity of acetylene partial hydrogenation. Different experimental techniques such as atomic absorption spectroscopy, surface area measurement and gas chromatography have been utilized to characterize chemical, structural and catalytic pro...

متن کامل

Asymmetric hydrogenation of heteroaromatic compounds.

Asymmetric hydrogenation of heteroaromatic compounds has emerged as a promising new route to saturated or partially saturated chiral heterocyclic compounds. In this Account, we outline recent advances in asymmetric hydrogenation of heteroaromatic compounds, including indole, quinoline, isoquinoline, furan, and pyridine derivatives, using chiral organometallic catalysts and organocatalysts.

متن کامل

Acetophenone hydrogenation over a Pd catalyst in the presence of H2O and CO2.

The addition of carbon dioxide and water enhances acetophenone hydrogenation activity over an activated carbon-supported palladium catalyst, and 1-phenylethanol can be easily recovered without distillation and neutralization. Two liquid phases (water and acetophenone) are indispensable for enhancement of the hydrogenation rate.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: ????????? ??????????????? ?????????. ????? ???????

سال: 2021

ISSN: ['2518-718X', '2663-4872']

DOI: https://doi.org/10.31489/2021ch3/74-82